BINAP 1.1′-Binaphthyl-2.2′-diphemyl phosphine CAS 98327-87-8

Sinonimi

BINAP
Binap
(?-Binap
1.1′-Binaphthyl-2.2′-Diphemyl Phosphine
2,2′-BIS(DIPHENYLPHOSPHINO)-1,1′-BINAPHTHYL
(?-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl
Rac-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene
Racemic-2,2′-bis(diphenylphosphino)-1,1′-binaphthy
racemic-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl
S(-)-(1,1′-Binaphthalene-2,2′-Diyl)Bis(Diphenylphosphine)
RACEMIC-2,2”-BIS(DIPHENYLPHOSPHINO)-1,1”-BINAPHTHYL BINAP
2,2′-Bis-(diphenylphosphino)-1,1′-binaphthyl (Racemic BINAP)

CAS

98327-87-8

EINECS

619-338-0

InChIKey

MUALRAIOVNYAIW-UHFFFAOYSA-N

massa molare

622.69

Punto di fusione

283-286°C(lit.)

punto Boling

724.3±55.0 °C(Predicted)

Solubilità in acqua

Soluble in tetrahydrofuran, benzene and dichloromethane. Slightly soluble in ether, methanol and ethanol. Insoluble in water.

Solubilità

Chloroform (Slightly, Sonicated), Dichloromethane (Slightly, Heated),

Aspetto

White to beige powder

Colore

White to light beige

Merck

14,1223

BRN

5321443

Condizioni di conservazione

Keep in dark place,Inert atmosphere,Room temperature

Sensibile

Air Sensitive

MDL

MFCD00010805

Proprietà fisiche e chimiche

Melting point 280-285°C.

Utilizzo

Used for asymmetric hydrogenation catalysis, carbonyl reduction, etc. A ligand for the palladium-catalyzed arylamine coupling reaction for the preparation of desmethylthio-colchicine? cicatine. It can be used in combination with Cu(II) to catalyze the addition reaction of arylsulfonamide to produce styrene and olefins. It can also be used for palladium-catalyzed tripyridyl amine reaction.

Codici di rischio

36/37/38 – Irritating to eyes, respiratory system and skin.

Descrizione della sicurezza

S22 – Do not breathe dust.
S24/25 – Avoid contact with skin and eyes.
S37/39 – Wear suitable gloves and eye/face protection
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

WGK Germania

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